李法宝副教授
  • 作者:系统管理员    发布日期:2013-07-18    点击率:

   名:李法宝

出生年月:19786

职务职称:副教授,硕士生导师

专业方向:有机化学

办公电话:02750865342

Emaillfb0615@hubu.edu.cn

                                                                             

研究领域与兴趣:

富勒烯化学、过渡金属催化有机新反应、有机功能光电材料合成与应用

迄今为止,已在国内外重要期刊发表SCI权威论文45篇,其中27篇论文发表在影响因子大于3.0的国际期刊Organic Letters, The Journal of Organic Chemistry, Dalton Transactions, Organic & Biomolecular Chemistry, New Journal of Chemistry, RSC Advances上。此外,在著名百科全书Kirk-Othmer Encyclopedia of Chemical TechnologyEncyclopedia of Physical Organic Chemistry上撰写富勒烯专章各一部。期刊影响因子总和累计达到170左右。

                                                   

教育与研究经历:

2007.06–2010.06 在中国科学技术大学博士后流动站工作,2002.09–2007.06在中国科学技术大学有机化学专业硕博连读,获理学博士学位;1998.09–2002.07在曲阜师范大学化学专业学习,获理学学士学位;20107月加入湖北大学化学化工学院。现为湖北大学有机功能分子合成与应用教育部重点实验室研究人员。

                                                   

教学情况:

承担本科生《有机化学》、《有机化学实验》等课程教学及辅导工作

                                                   

承担项目与课题:

1.      主持国家自然科学基金:新型富勒烯碳杂化合物的合成及其衍生化研究 21102041

2.      主持湖北省教育厅科学技术研究计划重点项目:新型富勒烯反应的开发及其在光电材料合成中的应用研究(D20161007

3.      主持湖北省自然科学基金:新型富勒烯-卟啉光电材料研究(2014CFB550

4.      主持湖北省教育厅科学技术研究计划优秀中青年人才项目:新型含氮/氧富勒烯化合物的合成研究Q20120113

5.      主持有机功能分子合成与应用教育部重点实验室(湖北大学)开放基金:基于低成本醛/胺新型富勒烯反应的开发KLSAOFM1706

6.      主持有机功能分子合成与应用教育部重点实验室(湖北大学)开放基金:中性双膦铜(I)配合物电致发光材料的制备与应用(2016-KL-013

7.      主持有机功能分子合成与应用教育部重点实验室(湖北大学)开放基金:基于氮丙啶富勒烯新反应的开发(2013-KL-010

8.      主持湖北大学自然科学基金:新型富勒烯碳杂化合物的合成及其衍生化研究(2010

9.      指导湖北省高等学校2013年省级大学生创新创业训练计划:新型富勒烯碳杂化合物的合成与表征(201310512011(指导老师)

10.  指导湖北省高等学校2016年省级大学生创新创业训练计划:具有生物相容性的抗HIV病毒活性C60Cl6衍生物的合成与表征(201610512054)(指导老师)

11.  指导湖北省高等学校2017年省级大学生创新创业训练计划:基于低成本醛/胺新型富勒烯杂环化合物的合成研究201710512044)(指导老师)

12.  指导2017年有机化工新材料湖北省协同创新中心大学生创新创业训练计划:低成本醛、胺参与富勒烯新反应体系的构建(2017)(指导老师)

                                           

获奖与荣誉:

1. 中国科学院院长优秀奖(2007            

2. 中国科学院王宽诚博士后工作奖(2007  

3. 湖北大学“青年突击手”(2013

4. 指导本科生获湖北省第八届大学生化学(化工)学术创新成果报告会二等奖(2015

5. 湖北大学优秀班主任(2016

6. 指导本科生获湖北省第十届大学生化学(化工)学术创新成果报告会二等奖(2017

7.指导本科生获湖北省第十一届挑战杯大学生课外学术科技作品竞赛二等奖(2017

                                                   

表性成果:

1.      Jie Peng, Gang Huang, Hui-Juan Wang, Fa-Bao Li,* Cheng Huang, Jun-Jun Xiang, Yongshun Huang, Li Liu,* Chao-Yang Liu,*Abdullah M. Asiri, and Khalid A. Alamry, “TEMPO-Mediated Synthesis of Tetrahydropyridinofullerenes: Reaction of [60]Fullerene with α-Methyl-SubstitutedArylmethanamines and Aldehydes in the Presence of 4-Dimethylaminopyridine” J. Org. Chem.2018, 83, 85-95.

2.      Jie Peng, Jun-Jun Xiang, Hui-Juan Wang, Fa-Bao Li,*Yong-Shun Huang, Li Liu,* Chao-Yang Liu,*Abdullah M. Asiri, and Khalid A. Alamry, “DMAP-Mediated Synthesis of Fulleropyrrolines: Reaction of [60]Fullerene with Aromatic Aldehydes and Arylmethanamines in the Absence or Presence of Manganese(III) Acetate” J. Org. Chem.2017, 82, 9751-9764.

3.      Meng Zhang, Hui-Juan Wang, Fa-Bao Li,* Xin-Xin Zhong, Yong-Shun Huang, Li Liu,* Chao-Yang Liu,* Abdullah M. Asiri, and Khalid A. Alamry, “Synthesis of 2-Aryl-5-alkyl-fulleropyrrolidines: Metal-Free-Mediated Reaction of [60]Fullerene with Aromatic Aldehydes and Inactive Primary Amines ”, J. Org. Chem. 2017, 82, 8617-8627.

4.      Jun-Jun Xiang, Cheng Huang, Hui-Juan Wang, Fa-Bao Li,* Ji-Long Shi, Yong-Shun Huang, Li Liu,* Chao-Yang Liu,* Abdullah M. Asiri, and Khalid A. Alamry, “Metal-free-mediated synthesis of fulleropyrrolines by the reaction of [60]fullerene with b-substituted ethylamines”, New J. Chem. 2017,41, 8725-8728.

5.      Fa-Bao Li and Guan-Wu Wang,* “Function Oriented Molecular Design: Fullerenes and Related Carbon Materials”, in Encyclopedia of Physical Organic Chemistry, Zerong Wang, Ed., John Wiley & Sons Inc., Hoboken, Volume 3, Chapter 9, 2017, 1-75. Online ISBN: 9781118470459. (Invited Book Chapter)

6.      Jun Wu, Chun-Xiang Liu, Hui-Juan Wang, Fa-Bao Li,* Ji-Long Shi, Li Liu, Jia-Xing Li,* Chao-Yang Liu,* and Yong-Shun Huang, “Cu(OAc)2-Mediated Reaction of [60]Fullerene with Aldehydes and Primary Amines for the Synthesis of Fulleropyrrolines”, J. Org. Chem. 2016, 81, 9296-9307.

7.      Ji-Long Shi, Xiao-Feng Zhang, Hui-Juan Wang, Fa-Bao Li,* Xin-Xin Zhong, Chun-Xiang Liu, Li Liu,* Chao-Yang Liu,* Hai-Mei Qin,* and Yong-Shun Huang “A Protocol for the Preparation of 2,5-Diaryl Fulleropyrrolidines: Thermal Reaction of [60]Fullerene with Aromatic Aldehydes and Arylmethanamines”, J. Org. Chem.2016, 81, 7662-7674. (Highlight as Hot article in August 2016)

8.      Hong-Yu Zhang, Hui-Juan Wang, Fa-Bao Li,* Chun-Xiang Liu, Xiao-Feng Zhang, Li Liu,* and Chao-Yang Liu* “Facile Access to 2,5-Diaryl Fulleropyrrolidines: Magnesium Perchlorate-Mediated Reaction of [60]Fullerene with Arylmethylamines and Arylaldehydes” RSC Adv. 2016, 6, 79095-79105.

9.      Ji-Long Shi, Fa-Bao Li,* Xiao-Feng Zhang, Jun Wu, Hong-Yu Zhang, Jie Peng, Chun-Xiang Liu, Li Liu,* Ping Wu, and Jia-Xing Li “Synthesis and Functionalization of Symmetrical 2,5-Diaryl Fulleropyrrolidines: Ferric Perchlorate-Mediated One-Step Reaction of [60]Fullerene with Arylmethanamines”,J. Org. Chem. 2016, 81, 1769-1777. (Highlight as Hot article in February 2016)

10.  Xiao-Feng Zhang, Fa-Bao Li,* Ji-Long Shi, Jun Wu, and Li Liu,* “Ferric Perchlorate-Mediated One-Step Reaction of [60]Fullerene with Primary Amides for the Synthesis of Fullerooxazoles New J. Chem. 2016,40, 1626-1632. (Abstracted by Cheminform 2016, 15-131)

11.  Tong–Xin Liu, Fa–Bao Li, Dian-Bing Zhou, and Guan–Wu Wang* “Ferric Perchlorate-Promoted Reaction of [60]Fullerene with N-Sulfonyl Aldimines: Synthesis and Functionalization of Fulleroxazolidines”, J. Org. Chem. 2015, 80, 11986-11992.

12.  Xiao-Feng Zhang, Fa-Bao Li,* Jun Wu, Ji-Long Shi, Zhan Liu, and Li Liu,* “Synthesis of Fullerene-Fused Dioxanes/Dioxepanes: Ferric Perchlorate Mediated One-Step Reaction of [60]Fullerene with Diols J. Org. Chem. 2015,80, 6037-6043. (Highlighted by X-MOL: http://www.x-mol.com/news/655)

13.  Jun Wu, Fa-Bao Li,* Xiao-Feng Zhang, Ji-Long Shi, and Li Liu,* “TsOH-Mediated Reaction of Aziridinofullerene with Diols for the Preparation of Fullerene-Fused Dioxygenated Ring Compounds” RSC Adv. 2015, 5, 30549-30554.

14.  Xun You,Fa–Bao Li, and Guan–Wu Wang,* “Synthesis of Ortho Acid Ester-Type 1,3-Dioxolanofullerenes: Radical Reaction of [60]Fullerene with Halocarboxylic Acids Promoted by Lead(IV) Acetate” J. Org. Chem. 2014, 79, 11155-11160.

15.  Fa-Bao Li,* Ye-Fei Zhu, Xiao-Feng Zhang, Ji-Long Shi, Jun Wu, Liu Chen, Xiao-Xue Liang, and Li Liu,* “Synthesis of Oxazolidinofullerenes and Thiazolidinofullerenes: Novel Reaction [60]Fullerene with Isocyanates and  Isothiocyanates Promoted by Ferric Perchlorate”, RSC Adv. 2014, 4, 48085-48094. (Abstracted by Cheminform 2015, 06-115)

16.  Hai-Tao Yang,* Meng-Lei Xing, Ye-Fei Zhu, Xiao-Qiang Sun, Jiang Cheng, Chun-Bao Miao, and Fa-Bao Li,* “BF3·Et2O-Catalyzed Formal [3+2] Reaction of Aziridinofullerenes with Carbonyl Compounds”, J. Org. Chem. 2014, 79, 1487–1492. (Abstracted by Cheminform 2014, 29-152)

17.  Fa-Bao Li and Guan-Wu Wang,* “Fullerenes”, in Kirk-Othmer Encyclopedia of Chemical Technology, Arza Seidel, Ed., Wiley-Blackwell: Hoboken, 2013, pp. 1-89. Online ISBN: 9780471238966. (Invited Book Chapter)

18.  Fa–Bao Li, Xun You, Tong–Xin Liu, and Guan–Wu Wang* “Fullerenyl Boronic Esters: Ferric Perchlorate–Mediated Synthesis and Functionalization”, Org. Lett. 2012,14, 1800–1803.

19.  Fa–Bao Li, Xun You, and Guan–Wu Wang* “Ferric Perchlorate–Mediated Synthesis of 1,2–Fullerenols C60(OCOR)(OH)”, J. Org. Chem. 2012, 77, 6643–6647.

20.  Fa–Bao Li, San–E Zhu, Xun You, and Guan–Wu Wang* “Ferric Perchlorate–Promoted Reaction of [60]Fullerene with β–Keto Esters”, Chin. Sci. Bull. 2012, 57, 2269–2272. (Highlighted as Cover)

21.  Fa–Bao Li and Guan–Wu Wang* “Ferric Perchlorate–Mediated Radical Reactions of [60]Fullerene”, Sci. China Chem. 2012, 55, 2009–2017.

22.  Guan–Wu Wang* and Fa–Bao Li “Transition Metal Salt–Mediated Radical Reactions of [60]Fullerene”, Curr. Org. Chem. 2012, 16, 1109–1127. (Abstracted by Cheminform 2012, 38-251)

23.  Tong–Xin Liu, Fa–Bao Li, and Guan–Wu Wang* “Synthesis of [60]Fullerene–Fused Tetrahydronaphthalene and Indane Derivatives via a Pathway Switched by Aluminum Chloride”, Org. Lett. 2011, 13, 6130–6133.

24.  Fa–Bao Li, Xun You, and Guan–Wu Wang* “Synthesis of Disubstituted [60]Fullerene–Fused Lactones: Ferric Perchlorate–Promoted Reaction of [60]Fullerene with Malonate Esters”, Org. Lett. 2010, 12, 48964899. (Highlighted by Synfacts 2011, 1, 0038)

25.  Fa–Bao Li, Tong–Xin Liu, Xun You, and Guan–Wu Wang* “A Facile Access to [60]Fullerene–Fused 1,3–Dioxolanes: Reaction of [60]Fullerene with Aldehydes/Ketones Promoted by Ferric Perchlorate”, Org. Lett. 2010,12, 3258–3261.

26.  Fa–Bao Li, San–E Zhu, and Guan–Wu Wang* “Manganese(III) Acetate–Mediated  Radical Reaction of [60]Fullerene with Bromoacetic Acid, 3–Chloropropionic Acid or 1–Naphthylacetic Acid”, Chin. Sci. Bull. 2010, 55, 2909–2914.

27.  Fa–Bao Li, Tong–Xin Liu, Yong–Shun Huang, and Guan–Wu Wang* “Synthesis of Fullerene–Fused Lactones and Fullerenyl Esters: Radical Reaction of [60]Fullerene with Carboxylic Acids Promoted by Manganese(III) Acetate and Lead(IV) Acetate”, J. Org. Chem. 2009, 74, 7743–7749.

28.  Fa–Bao Li, Tong–Xin Liu, and Guan–Wu Wang* “Synthesis of Fullerooxazoles: Novel Reactions of [60]Fullerene with Nitriles Promoted by Ferric Perchlorate”, J. Org. Chem. 2008, 73, 6417–6420. (Abstracted by Cheminform 2008, 14-272)

29.  Guan–Wu Wang,* Fa–Bao Li, and Yu Xu “Novel Functionalizations of [60]Fullerene–Fused Lactones”, J. Org. Chem. 2007, 72, 47744778.(Abstracted by Cheminform 2007, 43-098)

30.  Guan–Wu Wang,* Fa–Bao Li, Zhong–Xiu Chen, Ping Wu, Bin Cheng, and Yu Xu “Synthesis of [60]Fullerene Acetals and Ketals: Reaction of [60]Fullerene with Aldehydes/Ketones and Alkoxides”, J. Org. Chem. 2007, 72, 47794783. (Abstracted by Cheminform 2007, 43-099)

31.  Guan–Wu Wang* and Fa–Bao Li “Radical Reactions of [60]Fullerene–Mediated by Manganese(III) Acetate Dihydrate”, J. Nanosci. Nanotech. 2007, 7, 1162–1175. (Abstracted by Cheminform 2008, 14-272)

32.  Guan–Wu Wang,* Fa–Bao Li, and Ting–Hu Zhang “[60]Fullerene–Fused Lactones: Manganese(III) Acetate–Mediated Synthesis and Novel Reductive Ring Opening”, Org. Lett. 2006, 8, 1355–1358. (Abstracted by Cheminform 2006, 33-120)

33.  Guan–Wu Wang* and Fa–Bao Li “Cu(II) Acetate– and Mn(III) Acetate–Mediated Radical Reactions of [60]Fullerene with Ketonic Compounds”, Org. Biomol. Chem. 2005, 3, 794–797.