李法宝副教授
  • 作者:系统管理员    发布日期:2013-07-18    点击率:

   名:李法宝

出生年月:19786

职务职称:副教授,硕士生导师

专业方向:有机化学

办公电话:02750865342

Emaillfb0615@hubu.edu.cn

                                                                              

富勒烯化学、过渡金属催化有机新反应、有机功能光电材料合成与应用

迄今为止,已在国内外重要期刊发表SCI权威论文54篇,其中22篇论文发表在影响因子大于4.8的有机化学著名期刊Organic Letters, Advanced Synthesis & Catalysis, The Journal of Organic Chemistry上。此外,在著名百科全书Kirk-Othmer Encyclopedia of Chemical TechnologyEncyclopedia of Physical Organic Chemistry上撰写富勒烯专章各一部。期刊影响因子总和累计达到200左右。

                                                                              

教育与研究经历:

22007.06–2010.06 在中国科学技术大学博士后流动站工作,2002.09–2007.06在中国科学技术大学有机化学专业硕博连读,获理学博士学位;1998.09–2002.07在曲阜师范大学化学专业学习,获理学学士学位;20107月加入湖北大学化学化工学院。现为湖北大学有机功能分子合成与应用教育部重点实验室研究人员。

                                                                                          

教学情况:

承担本科生《有机化学》、《有机化学实验》等课程教学及辅导工作

                                                                              

承担项目与课题:

1. 主持国家自然科学基金:新型富勒烯碳杂化合物的合成及其衍生化研究(21102041

2. 主持湖北省教育厅科学技术研究计划重点项目:新型富勒烯反应的开发及其在光电材料合成中的应用研究(D20161007

3. 主持湖北省自然科学基金:新型富勒烯-卟啉光电材料研究(2014CFB550

4. 主持湖北省教育厅科学技术研究计划优秀中青年人才项目:新型含氮/氧富勒烯化合物的合成研究(Q20120113

5. 主持教育部与湖北兴发化工集团股份有限公司产学合作协同育人项目:新型富勒烯复合材料在污水处理中的除磷研究(201801081007

6. 主持硅酸盐建筑材料国家重点实验室(武汉理工大学)开放基金:富勒烯衍生物对钙钛矿光伏玻璃的界面调控(SYSJJ2019-10

7. 主持有机功能分子合成与应用教育部重点实验室(湖北大学)开放基金:基于低成本醛/胺新型富勒烯反应的开发(KLSAOFM1706

8. 主持有机功能分子合成与应用教育部重点实验室(湖北大学)开放基金:基于富勒烯新型光电材料的合成及性能研究(2015-KL-005

9. 主持有机功能分子合成与应用教育部重点实验室(湖北大学)开放基金:基于氮丙啶富勒烯新反应的开发(2013-KL-010

10.主持湖北大学自然科学基金:新型富勒烯碳杂化合物的合成及其衍生化研究(2010

                                                                             

获奖与荣誉:

1. 中国科学院院长优秀奖(2007            

2. 中国科学院王宽诚博士后工作奖(2007  

3. 湖北大学“青年突击手”(2013

4. 指导本科生获湖北省第八届大学生化学(化工)学术创新成果报告会二等奖(2015

5. 湖北大学优秀班主任(2016

6. 指导本科生获湖北省第十届大学生化学(化工)学术创新成果报告会二等奖(2017

7.指导本科生获湖北省第十一届挑战杯大学生课外学术科技作品竞赛二等奖(2017

8. 指导本科生获湖北省第十一届大学生化学(化工)学术创新成果报告会一等奖(2018

9. 指导本科生获湖北省第十一届大学生化学(化工)学术创新成果报告会二等奖(2018

                                                                              

表性成果:

1. Yun-Fei Li, Duo Zhang, Hui-Juan Wang, Fa-Bao Li,* Liang Sun, Li Liu, Chao-Yang Liu,* Abdullah M. Asiri, and Khalid A. Alamry, “Metal-Free Synthesis of N-Alkyl-2,5-Unsubstituted/Monosubstituted Fulleropyrrolidines: Reaction of [60]Fullerene with Polyformaldehyde and Amines” J. Org. Chem. 2019, 84, DOI: 10.1021/acs.joc.9b00083.

2. Gang Huang, Meng Zhang, Hui-Juan Wang, Fa-Bao Li,* Fei Yang, Li Liu, Chao-Yang Liu,* Abdullah M. Asiri, and Khalid A. Alamry, “Metal-Free Synthesis of Fulleropyrrolidin-2-ols: Novel Reaction of [60]Fullerene with Amines and 2,2-Disubstituted Acetaldehydes” Org. Biomol. Chem. 2018, 16, 7648-7656.

3. Meng Zhang, Hui-Juan Wang, Fa-Bao Li,* Xin-Xin Zhong, Yongshun Huang, Li Liu,* Chao-Yang Liu,* Abdullah M. Asiri, and Khalid A. Alamry, “Stereoselective Synthesis of N-Ethyl-2-Arylvinyl-5-Methyl Fulleropyrrolidines: Reaction of [60]Fullerene with Aromatic Aldehydes and Triethylamine/Diethylamine in the Absence or Presence of Manganese(III) Acetate” Org. Biomol. Chem. 2018, 16, 2975-2985. 

4. Cheng Huang, Gang Huang, Hui-Juan Wang, Fa-Bao Li,* Zhen Wang, Yongshun Huang, Li Liu, and Chao-Yang Liu,* “N-Alkylation of Fulleropyrrolidines by Aminomethylation Reaction of Ketones/Arylboronic Acids” Adv. Synth. Catal. 2018, 360, 3732-3750.

5. Jie Peng, Gang Huang, Hui-Juan Wang, Fa-Bao Li,* Cheng Huang, Jun-Jun Xiang, Yongshun Huang, Li Liu,* Chao-Yang Liu,* Abdullah M. Asiri, and Khalid A. Alamry, “TEMPO-Mediated Synthesis of Tetrahydropyridinofullerenes: Reaction of [60]Fullerene with α-Methyl-Substituted Arylmethanamines and Aldehydes in the Presence of 4-Dimethylaminopyridine” J. Org. Chem. 2018, 83, 85-95.

6. Jie Peng, Jun-Jun Xiang, Hui-Juan Wang, Fa-Bao Li,* Yong-Shun Huang, Li Liu,* Chao-Yang Liu,* Abdullah M. Asiri, and Khalid A. Alamry, “DMAP-Mediated Synthesis of Fulleropyrrolines: Reaction of [60]Fullerene with Aromatic Aldehydes and Arylmethanamines in the Absence or Presence of Manganese(III) Acetate” J. Org. Chem. 2017, 82, 9751-9764.

7. Meng Zhang, Hui-Juan Wang, Fa-Bao Li,* Xin-Xin Zhong, Yong-Shun Huang, Li Liu,* Chao-Yang Liu,* Abdullah M. Asiri, and Khalid A. Alamry, “Synthesis of 2-Aryl-5-alkyl-fulleropyrrolidines: Metal-Free-Mediated Reaction of [60]Fullerene with Aromatic Aldehydes and Inactive Primary Amines ”, J. Org. Chem. 2017, 82, 8617-8627.

8. Fa-Bao Li and Guan-Wu Wang,* “Function Oriented Molecular Design: Fullerenes and Related Carbon Materials”, in Encyclopedia of Physical Organic Chemistry, Zerong Wang, Ed., John Wiley & Sons Inc., Hoboken, Volume 3, Chapter 9, 2017, 1-75. Online ISBN: 9781118470459. (Invited Book Chapter)

9. Jun Wu, Chun-Xiang Liu, Hui-Juan Wang, Fa-Bao Li,* Ji-Long Shi, Li Liu, Jia-Xing Li,* Chao-Yang Liu,* and Yong-Shun Huang, “Cu(OAc)2-Mediated Reaction of [60]Fullerene with Aldehydes and Primary Amines for the Synthesis of Fulleropyrrolines”, J. Org. Chem. 2016, 81, 9296-9307.

10. Ji-Long Shi, Xiao-Feng Zhang, Hui-Juan Wang, Fa-Bao Li,* Xin-Xin Zhong, Chun-Xiang Liu, Li Liu,* Chao-Yang Liu,* Hai-Mei Qin,* and Yong-Shun Huang “A Protocol for the Preparation of 2,5-Diaryl Fulleropyrrolidines: Thermal Reaction of [60]Fullerene with Aromatic Aldehydes and Arylmethanamines”, J. Org. Chem. 2016, 81, 7662-7674. 

11. Ji-Long Shi, Fa-Bao Li,* Xiao-Feng Zhang, Jun Wu, Hong-Yu Zhang, Jie Peng, Chun-Xiang Liu, Li Liu,* Ping Wu, and Jia-Xing Li “Synthesis and Functionalization of Symmetrical 2,5-Diaryl Fulleropyrrolidines: Ferric Perchlorate-Mediated One-Step Reaction of [60]Fullerene with Arylmethanamines”, J. Org. Chem. 2016, 81, 1769-1777.

12. Xiao-Feng Zhang, Fa-Bao Li,* Jun Wu, Ji-Long Shi, Zhan Liu, and Li Liu,* “Synthesis of Fullerene-Fused Dioxanes/Dioxepanes: Ferric Perchlorate Mediated One-Step Reaction of [60]Fullerene with Diols” J. Org. Chem. 2015, 80, 6037-6043.

13. Tong–Xin Liu, Fa–Bao Li, Dian-Bing Zhou, and Guan–Wu Wang* “Ferric Perchlorate-Promoted Reaction of [60]Fullerene with N-Sulfonyl Aldimines: Synthesis and Functionalization of Fulleroxazolidines”, J. Org. Chem. 2015, 80, 11986-11992. 

14. Xun You, Fa–Bao Li, and Guan–Wu Wang,* “Synthesis of Ortho Acid Ester-Type 1,3-Dioxolanofullerenes: Radical Reaction of [60]Fullerene with Halocarboxylic Acids Promoted by Lead(IV) Acetate” J. Org. Chem. 2014, 79, 11155-11160. 

15. Hai-Tao Yang,* Meng-Lei Xing, Ye-Fei Zhu, Xiao-Qiang Sun, Jiang Cheng, Chun-Bao Miao, and Fa-Bao Li,* “BF3·Et2O-Catalyzed Formal [3+2] Reaction of Aziridinofullerenes with Carbonyl Compounds”, J. Org. Chem. 2014, 79, 1487–1492.

16. Fa-Bao Li and Guan-Wu Wang,* “Fullerenes”, in Kirk-Othmer Encyclopedia of Chemical Technology, Arza Seidel, Ed., John Wiley & Sons Inc., Hoboken, 2013, pp. 1-89. Online ISBN: 9780471238966. (Invited Book Chapter)

17. Fa–Bao Li, Xun You, Tong–Xin Liu, and Guan–Wu Wang* “Fullerenyl Boronic Esters: Ferric Perchlorate–Mediated Synthesis and Functionalization”, Org. Lett. 2012, 14, 1800–1803. 

18. Fa–Bao Li, Xun You, and Guan–Wu Wang* “Ferric Perchlorate–Mediated Synthesis of 1,2–Fullerenols C60(OCOR)(OH)”, J. Org. Chem. 2012, 77, 6643–6647. 

19. Tong–Xin Liu, Fa–Bao Li, and Guan–Wu Wang* “Synthesis of [60]Fullerene–Fused Tetrahydronaphthalene and Indane Derivatives via a Pathway Switched by Aluminum Chloride”, Org. Lett. 2011, 13, 6130–6133. 

20. Fa–Bao Li, Xun You, and Guan–Wu Wang* “Synthesis of Disubstituted [60]Fullerene–Fused Lactones: Ferric Perchlorate–Promoted Reaction of [60]Fullerene with Malonate Esters”, Org. Lett. 2010, 12, 4896–4899. 

21. Fa–Bao Li, Tong–Xin Liu, Xun You, and Guan–Wu Wang* “A Facile Access to [60]Fullerene–Fused 1,3–Dioxolanes: Reaction of [60]Fullerene with Aldehydes/Ketones Promoted by Ferric Perchlorate”, Org. Lett. 2010, 12, 3258–3261. 

22. Fa–Bao Li, Tong–Xin Liu, Yong–Shun Huang, and Guan–Wu Wang* “Synthesis of Fullerene–Fused Lactones and Fullerenyl Esters: Radical Reaction of [60]Fullerene with Carboxylic Acids Promoted by Manganese(III) Acetate and Lead(IV) Acetate”, J. Org. Chem. 2009, 74, 7743–7749. 

23. Fa–Bao Li, Tong–Xin Liu, and Guan–Wu Wang* “Synthesis of Fullerooxazoles: Novel Reactions of [60]Fullerene with Nitriles Promoted by Ferric Perchlorate”, J. Org. Chem. 2008, 73, 6417–6420. 

24. Guan–Wu Wang,* Fa–Bao Li, and Yu Xu “Novel Functionalizations of [60]Fullerene–Fused Lactones”, J. Org. Chem. 2007, 72, 4774–4778.

25. Guan–Wu Wang,* Fa–Bao Li, Zhong–Xiu Chen, Ping Wu, Bin Cheng, and Yu Xu “Synthesis of [60]Fullerene Acetals and Ketals: Reaction of [60]Fullerene with Aldehydes/Ketones and Alkoxides”, J. Org. Chem. 2007, 72, 4779–4783.

26. Guan–Wu Wang,* Fa–Bao Li, and Ting–Hu Zhang “[60]Fullerene–Fused Lactones: Manganese(III) Acetate–Mediated Synthesis and Novel Reductive Ring Opening”, Org. Lett. 2006, 8, 1355–1358.